Aside from dispersion, materials usually have the same index of refraction for all orientations of the electric field in the light. However, some materials, usually nearly pure crystals, have two indices of refraction for the same wavelength of light. The difference is due only to the orientation of the light's electric field. Therefore, light with its electric field oscillating in the vertical direction experiences a different index of refraction from the index of refraction for an electric field oscillating in the horizontal direction. This is called birefringence. (Source: Optics for Dummies by Duree)
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